More than £20.4 million was paid in support to people in Clackmannanshire.
The Scottish Government provided the support across 14 benefits in the financial year between April 1, 2023, and March 31, 2024.
This is part of the £1.9 billion in direct payments throughout Scotland.
The 14 payments, seven of which are not available anywhere else in the UK, provide 'essential support' for people because of the rising cost of living.
Other notable points in the report was that the Winter Heating Payment was paid to 400,000 people by February of this year.
Scottish Child Payment was supporting more than 329,000 children and young people at the end of March 2024.
Eligible people who get benefits include carers, disabled people and families, pensioners, young people starting jobs, and people who need help paying for a funeral.
Shirley-Anne Sommerville, Cabinet Secretary for Social Justice said: "We are committed to tackling poverty and supporting people throughout Scotland.
"At a time when families are struggling with the ongoing cost-of-living crisis we have been delivering 14 benefits, seven of which are only available in Scotland.
"Winter Heating Payment is a reliable annual payment to people on low incomes in Scotland, including pensioners receiving Pension Credit.
"We continue to offer vital support to families through our five family payments, including Scottish Child Payment, which was helping support more than 329,000 children and young people by the end of 2023-24.
"We are focused on ensuring people get the money they are entitled to and that we deliver these payments while treating people with dignity, fairness and respect."
Social Security Scotland delivered payments worth £463 million to help families on low incomes with their living costs through five family payments, which includes Best Start Foods, the three Best Start Grants, and Scottish Child Payment.
The results of the organisation’s annual Client Survey have also been published, showing that 90 per cent of people who responded and received a benefit payment from Social Security Scotland say their overall experience was ‘very good’ or ‘good’.
A further 89 per cent said they were treated with kindness.
David Wallace, Social Security Scotland Chief Executive said: "While our service has continued to expand significantly, our clients remain at the heart of everything we do.
"We have focused on delivering new payments to people across Scotland including Carer Support Payment, while ensuring we give our clients an improved experience.
"This year, we have reduced call waiting and processing times and made it easier for people to submit supporting information for disability benefit applications.
"As the number of people we serve grows, I am delighted we have maintained high client satisfaction rates with our annual Client Survey showing 90 per cent of people who received a payment from us saying their overall experience was ‘very good’ or ‘good’."
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